The kinetic theory explains temperature as the collective effect of the motion of many particles. Usually these collective effects are only observed as the average behavior of millions of billions of particles which all share a common pool of energy. According to kinetic theory, all of the particles which share a common pool of energy are called members of an ensemble. Each member is free to use a random amount of energy from the shared pool, but one particle using a lot of energy leaves less energy for the other particles. This means that the majority of the particles in an ensemble have energies close to or less than the average energy, while a few of them have energies much larger than the average. When the energy distribution of the ensemble reaches a steady state, the ensemble is said to be in thermal equilibrium. The average energy per particle for an ensemble in equilibrium is called temperature, according to the kinetic theory. The energy distribution of the members of an ensemble in thermal equilibrium at temperature T is an exponential distribution with an average energy kT, where k (Boltzmann's constant) is there in order to convert temperature from degrees Kelvin to units of energy (Joules). | The kinetic theory explains temperature as the collective effect of the motion of many particles. Usually these collective effects are only observed as the average behavior of millions of billions of particles which all share a common pool of energy. According to kinetic theory, all of the particles which share a common pool of energy are called members of an ensemble. Each member is free to use a random amount of energy from the shared pool, but one particle using a lot of energy leaves less energy for the other particles. This means that the majority of the particles in an ensemble have energies close to or less than the average energy, while a few of them have energies much larger than the average. When the energy distribution of the ensemble reaches a steady state, the ensemble is said to be in thermal equilibrium. The average energy per particle for an ensemble in equilibrium is called temperature, according to the kinetic theory. The energy distribution of the members of an ensemble in thermal equilibrium at temperature T is an exponential distribution with an average energy kT, where k (Boltzmann's constant) is there in order to convert temperature from degrees Kelvin to units of energy (Joules). |